Let's say you currently have the reports set to save in "F:\Reports". F is a mapped drive to some network location. Its UNC path is going to look something like \\SERVERNAME\FOLDERNAME. You need to determine the UNC path for that mapped drive and replace "F:" in your RRD with that UNC path. So instead of saving the reports to "F:\Reports" you would be saving to "\\SERVERNAME\FOLDERNAME\Reports".
Fortunately, it's easy to get the UNC path. Open a command prompt. (Start > type "cmd" > hit Enter.) In the command prompt window, type "net use" and hit Enter. You'll see your mapped drives listed under the "Local" heading. The UNC path equivalent for each is listed under "Remote".